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Lactonamycin, a new antimicrobial antibiotic produced by Streptomyces rishiriensis MJ773-88K4. II. Structure determination. 1999
N Matsumoto, and
T Tsuchida, and
H Nakamura, and
R Sawa, and
Y Takahashi, and
H Naganawa, and
H Iinuma, and
T Sawa, and
T Takeuchi, and
M Shiro
Institute of Microbial Chemistry, Tokyo, Japan.
The absolute structure of a new antibiotic lactonamycin is described. The NMR studies deduced one of four possible structures for the aglycon attached by a rhodinose through glycosidic bond. The stereochemistry of the sugar obtained by an acid hydrolysis was determined to be L-form by measuring optical rotation. The stereochemistry of the aglycon was determined by X-ray crystallographic analysis.
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