-transparent.png){kind=logo}
A study of the adsorptive stripping voltammetry of cadmium on a mercury drop electrode is reported in which 2-mercapto-5-phenyl-amino-1,3,4-thiadiazole (MPATD), synthesized at home has been used as a chelating agent. The most suitable operating conditions and parameters such as buffer, pH, deposition potential, deposition time, ligand concentration, scan rate and others were selected and the determination of cadmium from aqueous solutions using the standard additions method was possible. As validation criteria, the linearity and range, repeatability of the signal, repeatability of the concentration and accuracy were investigated. A limit of detection of 4.67 x 10(-10) M and a limit of quantification of 1.55 x 10(-9) M were achieved. The interference of other metals and organic substances was studied. Concerning a possible catalytic effect, no one was found. The method was designed in order to determine Cd from biological samples.
P Suciu, and
M Vega, and
L Roman
March 2003,
Journal of pharmaceutical and biomedical analysis,
P Suciu, and
M Vega, and
L Roman
June 1990,
The Analyst,
P Suciu, and
M Vega, and
L Roman
August 2009,
Journal of hazardous materials,
P Suciu, and
M Vega, and
L Roman
July 1999,
Talanta,
P Suciu, and
M Vega, and
L Roman
November 1987,
Talanta,
P Suciu, and
M Vega, and
L Roman
May 2002,
Bioelectrochemistry (Amsterdam, Netherlands),
P Suciu, and
M Vega, and
L Roman
March 1987,
The Analyst,
P Suciu, and
M Vega, and
L Roman
February 2004,
Talanta,
P Suciu, and
M Vega, and
L Roman
September 2002,
Talanta,
P Suciu, and
M Vega, and
L Roman
April 2009,
Bioelectrochemistry (Amsterdam, Netherlands),
