New syntheses of the rice moth and stink bug pheromones by employing (2R, 6S)-7-acetoxy-2,6-dimethyl-1-heptanol as a building block. 2000

Y Nakamura, and K Mori
Department of Chemistry, Faculty of Science, Science University of Tokyo, Japan.

(2R, 6R, 10R)-6,10,14-Trimethyl-2-pentadecanol, the female pheromone of the rice moth (Corcyra cephalonica), methyl (2R, 6R, 10R)-2,6,10-trimethyltridecanoate, the male pheromone of the stink bug (Euschistus heros) were synthesized by employing (2R, 6S)-7-acetoxy-2,6-dimethyl-1-heptanol as the common chiral building block.

UI MeSH Term Description Entries
D008297 Male Males
D008956 Models, Chemical Theoretical representations that simulate the behavior or activity of chemical processes or phenomena; includes the use of mathematical equations, computers, and other electronic equipment. Chemical Models,Chemical Model,Model, Chemical
D009036 Moths Insects of the suborder Heterocera of the order LEPIDOPTERA. Antheraea,Giant Silkmoths,Giant Silkworms,Silkmoths, Giant,Silkworms, Giant,Antheraeas,Giant Silkmoth,Giant Silkworm,Moth,Silkmoth, Giant,Silkworm, Giant
D003651 Decanoates Salts and esters of the 10-carbon monocarboxylic acid-decanoic acid.
D005233 Fatty Alcohols Usually high-molecular-weight, straight-chain primary alcohols, but can also range from as few as 4 carbons, derived from natural fats and oils, including lauryl, stearyl, oleyl, and linoleyl alcohols. They are used in pharmaceuticals, cosmetics, detergents, plastics, and lube oils and in textile manufacture. (From McGraw-Hill Dictionary of Scientific and Technical Terms, 5th ed) Fatty Alcohol,Alcohol, Fatty,Alcohols, Fatty
D005260 Female Females
D000818 Animals Unicellular or multicellular, heterotrophic organisms, that have sensation and the power of voluntary movement. Under the older five kingdom paradigm, Animalia was one of the kingdoms. Under the modern three domain model, Animalia represents one of the many groups in the domain EUKARYOTA. Animal,Metazoa,Animalia
D012724 Sex Attractants Pheromones that elicit sexual attraction or mating behavior usually in members of the opposite sex in the same species. Copulins,Pheromones, Sexual,Sex Pheromones,Sexual Pheromone,Sex Attractant,Sex Pheromone,Attractant, Sex,Attractants, Sex,Pheromone, Sex,Pheromone, Sexual,Pheromones, Sex,Sexual Pheromones
D019850 Heptanol A colorless liquid with a fragrant odor. It is used as an intermediate, solvent and in cosmetics. 1-Heptanol,Alcohol, Heptyl,n-Heptanol,1 Heptanol,Heptyl Alcohol,n Heptanol

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