BIOMAT Database Logo BIOMAT Database Logo

Syntheses of daidzein-7-yl beta-D-glucopyranosiduronic acid and daidzein-4',7-yl di-beta-D-glucopyranosiduronic acid. 2001

P W Needs, and G Williamson
Institute of Food Research, Norwich Research Park, Colney, UK.

Syntheses of the title compounds--commonly known as 'daidzein 7-glucuronide' and 'daidzein 4',7-diglucuronide'--are described. Selective 7-deacetylation of 4',7-di-O-acetyldaidzein is employed.

UI MeSH Term Description Entries
D007529 Isoflavones 3-Phenylchromones. Isomeric form of FLAVONOIDS in which the benzene group is attached to the 3 position of the benzopyran ring instead of the 2 position. 3-Benzylchroman-4-One,3-Benzylidene-4-Chromanone,Homoisoflavone,Homoisoflavones,Isoflavone,Isoflavone Derivative,3-Benzylchroman-4-Ones,3-Benzylidene-4-Chromanones,Isoflavone Derivatives,3 Benzylchroman 4 One,3 Benzylchroman 4 Ones,3 Benzylidene 4 Chromanone,3 Benzylidene 4 Chromanones,Derivative, Isoflavone,Derivatives, Isoflavone
D002851 Chromatography, High Pressure Liquid Liquid chromatographic techniques which feature high inlet pressures, high sensitivity, and high speed. Chromatography, High Performance Liquid,Chromatography, High Speed Liquid,Chromatography, Liquid, High Pressure,HPLC,High Performance Liquid Chromatography,High-Performance Liquid Chromatography,UPLC,Ultra Performance Liquid Chromatography,Chromatography, High-Performance Liquid,High-Performance Liquid Chromatographies,Liquid Chromatography, High-Performance
D005965 Glucuronates Derivatives of GLUCURONIC ACID. Included under this heading are a broad variety of acid forms, salts, esters, and amides that include the 6-carboxy glucose structure. Glucosiduronates,Glucuronic Acids,Acids, Glucuronic
D006031 Glycosylation The synthetic chemistry reaction or enzymatic reaction of adding carbohydrate or glycosyl groups. GLYCOSYLTRANSFERASES carry out the enzymatic glycosylation reactions. The spontaneous, non-enzymatic attachment of reducing sugars to free amino groups in proteins, lipids, or nucleic acids is called GLYCATION (see MAILLARD REACTION). Protein Glycosylation,Glycosylation, Protein
D000107 Acetylation Formation of an acetyl derivative. (Stedman, 25th ed) Acetylations
D015394 Molecular Structure The location of the atoms, groups or ions relative to one another in a molecule, as well as the number, type and location of covalent bonds. Structure, Molecular,Molecular Structures,Structures, Molecular

Related Publications

P W Needs, and G Williamson
Syntheses of chondroitin 4- and 6-sulfate pentasaccharide derivatives having a methyl beta-D-glucopyranosiduronic acid at the reducing end.
June 2000, Carbohydrate research,
P W Needs, and G Williamson
Synthesis of daidzein 7-O-beta-D-glucuronide-4'-O-sulfate.
November 2007, Steroids,
P W Needs, and G Williamson
Synthesis of p-acetamidophenyl beta-D-glucopyranosiduronic acid.
June 1969, Journal of the Chemical Society. Perkin transactions 1,
P W Needs, and G Williamson
Unsaturated sugars. I. Decarboxylative elimination of methyl 2,3-di-O-benzyl-alpha-D-glucopyranosiduronic acid to methyl 2,3-di-O-benzyl-4-deoxy-beta-L-threo-pent-4-enopyranoside.
October 1973, Carbohydrate research,
P W Needs, and G Williamson
[Biological effects of 4-[N.N-bis-(2-chlorethyl)-amino]-phenyl-O-beta-D-glucopyranosiduronic acid methylesters].
March 1977, Die Pharmazie,
P W Needs, and G Williamson
Glycosidation-anomerisation reactions of 6,1-anhydroglucopyranuronic acid and anomerisation of beta-D-glucopyranosiduronic acids promoted by SnCl(4).
January 2007, Chemistry (Weinheim an der Bergstrasse, Germany),
P W Needs, and G Williamson
Syntheses of di- and tripeptides containing 4-aminocyclohexanecarboxylic acid.
February 1975, The Journal of organic chemistry,
P W Needs, and G Williamson
[New way of synthetizing 4-/N,N-bis-(chloroethyl)-amino/-phenyl-beta-D-glucopyranosiduronic acid methyl ester].
January 1977, Die Pharmazie,
P W Needs, and G Williamson
[Studies on D-glucuronolactone derivatives. V. Synthesis of alkylaminoethyl beta-D-glucopyranosiduronic acid derivatives].
December 1965, Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan,
P W Needs, and G Williamson
The preparation of 5 beta-pregnane-3 alpha,17,20 alpha-triol 3 alpha-yl beta-D-glucopyranosiduronic acid and its [6,7-3H]-analogue.
March 1980, Journal of steroid biochemistry,
Copied contents to your clipboard!