Resolution and absolute configuration of naturally occurring auronols. 2001

R Bekker, and X C Li, and H N ElSohly, and A M Clark, and E V Brandt, and D Ferreira
Department of Chemistry, University of the Orange Free State, P.O. Box 339, Bloemfontein, 9300 South Africa.

Resolution of racemic 2-benzyl-2-hydroxy-1-benzofuran-3(2H)-ones (auronols) and CD data of the ensuing enantiomers permit assessment of the absolute configuration at the single stereocenter.

UI MeSH Term Description Entries
D002942 Circular Dichroism A change from planar to elliptic polarization when an initially plane-polarized light wave traverses an optically active medium. (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) Circular Dichroism, Vibrational,Dichroism, Circular,Vibrational Circular Dichroism
D001572 Benzofurans Compounds that contain a BENZENE ring fused to a furan ring. Coumarones,Diphenylbenzofuran
D019685 Rosales An order of the class MAGNOLIOPSIDA. Its members include some of the most known ornamental and edible plants of temperate zones including roses, apples, cherries, and peaches. Pittosporaceae,Pittosporum,Pittosporums,Rosale
D032462 Cycadopsida A class of vascular seed plants also known as gymnosperms in the subdivision spermatophytina. They have large cones and pinnate leaves. Examples are pines, spruces, cedars and sequoias. Gymnosperms,Cycadales,Cycadophyta,Cycadale,Cycadophytas,Gymnosperm

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