-transparent.png){kind=logo}
A negative-ion mode laser spray interface for use in liquid chromatography/mass spectrometry (LC/MS) has been developed and investigated. The laser spray gave sensitivities that were orders of magnitude better than the negative-ion electrospray for all samples investigated with the exception of sugars. Fragment ions, HSO(-4)and SO(-3), were formed from the laser-sprayed aqueous solution of cholesterol 3-sulfate sodium salt. This suggests that structural information may be obtained directly from the laser-spray mass spectra for thermally labile compounds.
Related Publications
K Hiraoka, and
Y Asakawa, and
Y Yamamoto, and
M Nakamura, and
K Ueda
June 2009,
Clinical chemistry,
K Hiraoka, and
Y Asakawa, and
Y Yamamoto, and
M Nakamura, and
K Ueda
August 2001,
Journal of chromatography. A,
K Hiraoka, and
Y Asakawa, and
Y Yamamoto, and
M Nakamura, and
K Ueda
January 2004,
Rapid communications in mass spectrometry : RCM,
K Hiraoka, and
Y Asakawa, and
Y Yamamoto, and
M Nakamura, and
K Ueda
December 1992,
Analytical biochemistry,
K Hiraoka, and
Y Asakawa, and
Y Yamamoto, and
M Nakamura, and
K Ueda
February 2004,
Analytical chemistry,
K Hiraoka, and
Y Asakawa, and
Y Yamamoto, and
M Nakamura, and
K Ueda
October 1988,
Biomedical & environmental mass spectrometry,
K Hiraoka, and
Y Asakawa, and
Y Yamamoto, and
M Nakamura, and
K Ueda
August 1993,
Journal of chromatography,
K Hiraoka, and
Y Asakawa, and
Y Yamamoto, and
M Nakamura, and
K Ueda
April 1985,
Analytical chemistry,
K Hiraoka, and
Y Asakawa, and
Y Yamamoto, and
M Nakamura, and
K Ueda
September 2004,
Analytical and bioanalytical chemistry,
K Hiraoka, and
Y Asakawa, and
Y Yamamoto, and
M Nakamura, and
K Ueda
February 2004,
Analytical and bioanalytical chemistry,
