Three heterotrinuclear Schiff base complexes of nickel(II) with cobalt(II), copper(II) and manganese(II). 2002

Filiz Ercan, and Orhan Atakol, and Cengiz Arici, and Ingrid Svoboda, and Hartmut Fuess
Department of Engineering Physics, Hacettepe University, Beytepe 06532, Ankara, Turkey. filiz@hacettepe.edu.tr

The title compounds, bis(dimethylformamide)-1 kappa O,3 kappa O-bis[mu-2,2'-[2,2'-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato]-1 kappa(4)N,N',O,O':2 kappa(2)O,O';2 kappa(2)O,:3 kappa(4)N,N'prime prime or minute,O,O'-di-mu-nitrito-1:2 kappa(2)N:O;2:3 kappa(2)O:N-dinickel(II)cobalt(II), [CoNi(2)(NO(2))(2)(C(19)H(22)N(2)O(2))(2)(C(3)H(7)NO)(2)], (I), -copper(II), [CuNi(2)(NO(2))(2)(C(19)H(22)N(2)O(2))(2)(C(3)H(7)NO)(2)], (II), and -manganese(II), [MnNi(2)(NO(2))(2)(C(19)H(22)N(2)O(2))(2)(C(3)H(7)NO)(2)], (III), consist of centrosymmetric linear heterotrinuclear metal complexes. The three complexes are isostructural. There are three bridges across the Ni-M atom pairs (M is Co(2+), Cu(2+) or Mn(2+)) in each complex, involving two O atoms of a mu-N,N'-bis(salicylidene)-2,2'-1,3-propanediaminate ligand and an N-O moiety of a mu-nitrito group. The coordination sphere around each metal atom, whether Co(2+), Cu(2+), Mn(2+) or Ni(2+), can be described as distorted octahedral. The Ni...M distances are 2.9988 (5) A in (I), 2.9872 (5) A in (II) and 3.0624 (8) A in (III).

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