Biomaterial Database

Energetic stabilization of d-camphor via weak neutral currents. 1999

P Lazzeretti, and R Zanasi, and F Faglioni

Dipartimento di Chimica, Università degli Studi, via G. Campi 183, 41100 Modena, Italy. lazzeret@unimo.it

It is shown via a series of numerical tests on the camphor molecule, C10H16O, that the naturally occurring d-enantiomer is energetically stabilized with respect to its mirror image by electroweak force. The calculated energy difference between enantiomers, about 1.5 x 10(-19) hartree, is roughly eight orders of magnitude smaller than the upper bound suggested by available spectroscopic investigations on the frequency of a spectroscopic transition. However, such a difference is about ten times larger than previous estimates of parity-violating energy contributions reported in the literature for other chiral molecules, which makes the idea of electroweak stabilization of one enantiomer more reliable than expected before.

UI	MeSH Term	Description	Entries
D008956	Models, Chemical	Theoretical representations that simulate the behavior or activity of chemical processes or phenomena; includes the use of mathematical equations, computers, and other electronic equipment.	Chemical Models,Chemical Model,Model, Chemical
D008958	Models, Molecular	Models used experimentally or theoretically to study molecular shape, electronic properties, or interactions; includes analogous molecules, computer-generated graphics, and mechanical structures.	Molecular Models,Model, Molecular,Molecular Model
D002164	Camphor	A bicyclic monoterpene ketone found widely in plants, especially CINNAMOMUM CAMPHORA. It is used topically as a skin antipruritic and as an anti-infective agent.	Camphor, (+-)-Isomer,Camphor, (1R)-Isomer,Camphor, (1S)-Isomer
D001703	Biophysics	The study of PHYSICAL PHENOMENA and PHYSICAL PROCESSES as applied to living things.	Mechanobiology
D013816	Thermodynamics	A rigorously mathematical analysis of energy relationships (heat, work, temperature, and equilibrium). It describes systems whose states are determined by thermal parameters, such as temperature, in addition to mechanical and electromagnetic parameters. (From Hawley's Condensed Chemical Dictionary, 12th ed)	Thermodynamic
D015233	Models, Statistical	Statistical formulations or analyses which, when applied to data and found to fit the data, are then used to verify the assumptions and parameters used in the analysis. Examples of statistical models are the linear model, binomial model, polynomial model, two-parameter model, etc.	Probabilistic Models,Statistical Models,Two-Parameter Models,Model, Statistical,Models, Binomial,Models, Polynomial,Statistical Model,Binomial Model,Binomial Models,Model, Binomial,Model, Polynomial,Model, Probabilistic,Model, Two-Parameter,Models, Probabilistic,Models, Two-Parameter,Polynomial Model,Polynomial Models,Probabilistic Model,Two Parameter Models,Two-Parameter Model
D055592	Biophysical Phenomena	The physical characteristics and processes of biological systems.	Biophysical Concepts,Biophysical Processes,Biophysical Phenomenon,Biophysical Process,Biophysical Concept,Concept, Biophysical,Concepts, Biophysical,Phenomena, Biophysical,Phenomenon, Biophysical,Process, Biophysical,Processes, Biophysical