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Irreversible thermodynamics of Poisson processes with reaction. 1999

V Méndez, and J Fort
Facultat de Ciències de la Salut, Universitat Internacional de Catalunya, Gomera s/n, 08190 Sant Cugat del Vallès, Barcelona, Catalonia, Spain.

A kinetic model is derived to study the successive movements of particles, described by a Poisson process, as well as their generation. The irreversible thermodynamics of this system is also studied from the kinetic model. This makes it possible to evaluate the differences between thermodynamical quantities computed exactly and up to second-order. Such differences determine the range of validity of the second-order approximation to extended irreversible thermodynamics.

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