Isotactic-b-syndiotactic stereoblock poly(methyl methacrylate) by chiral metallocene/Lewis acid hybrid catalysts. 2002

Andrew D Bolig, and Eugene Y-X Chen
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872, USA.

Stereoblock polymerization with chiral ansa-metallocene/strong Lewis acid hybrid catalysts capable of switching stereospecificity of the methyl methacrylate polymerization produces the highly stereoregular isotactic-b-syndiotactic stereoblock poly(methyl methacrylate).

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