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In the present study, we synthesized amylose-tris(phenylcarbamate), and used it as chiral stationary phase based on silica gel. This stationary phase offered a practically useful chiral separation medium. Amylose was allowed to react with an excess of phenylisocyanate in pyridine for 48 h. The obtained carbamate was dissolved in DMF and adsorbed on silica gel previously treated with 3-aminopropyltriethoxysilane. The mass ratio of the carbamate to the silica gel was 0.45/2.55. The four thio-glycidyl ethers were resolved on the amylose tris(phenylcarbamate) chiral stationary phase. Separation was carried out with a hexane/2-propanol mixture as mobile phase at a flow rate of 1.0 mL/min at room temperature. The effects of 2-propanol concentration on the retention and resolution have been investigated.
Z Zhou, and
Z Yu, and
T Niu, and
S Jiang, and
L Chen
November 2008,
Se pu = Chinese journal of chromatography,
Z Zhou, and
Z Yu, and
T Niu, and
S Jiang, and
L Chen
February 2006,
Journal of separation science,
Z Zhou, and
Z Yu, and
T Niu, and
S Jiang, and
L Chen
February 2010,
Se pu = Chinese journal of chromatography,
Z Zhou, and
Z Yu, and
T Niu, and
S Jiang, and
L Chen
September 2007,
Se pu = Chinese journal of chromatography,
Z Zhou, and
Z Yu, and
T Niu, and
S Jiang, and
L Chen
January 2013,
Methods in molecular biology (Clifton, N.J.),
Z Zhou, and
Z Yu, and
T Niu, and
S Jiang, and
L Chen
April 2006,
Journal of separation science,
Z Zhou, and
Z Yu, and
T Niu, and
S Jiang, and
L Chen
March 2006,
Se pu = Chinese journal of chromatography,
Z Zhou, and
Z Yu, and
T Niu, and
S Jiang, and
L Chen
November 2011,
Se pu = Chinese journal of chromatography,
Z Zhou, and
Z Yu, and
T Niu, and
S Jiang, and
L Chen
September 1998,
Se pu = Chinese journal of chromatography,
Z Zhou, and
Z Yu, and
T Niu, and
S Jiang, and
L Chen
April 2004,
Talanta,
