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A one-dimensional zigzag coordination polymer of diaqua(pyridine-2,3-dicarboxylato)cobalt(II). 2003

Hong Tao Zhang, and Xiao Zeng You
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, People's Republic of China.

The asymmetric unit of the title one-dimensional coordination polymer, catena-poly[[mu-pyridine-2,3-dicarboxylato-1kappaO:2kappa(2)N,O'-bis[diaquacobalt(II)]]-mu-pyridine-2,3-dicarboxylato-1kappa(2)N,O:2kappaO':1'kappaO'], [Co(C(7)H(3)NO(4))(H(2)O)(2)](n), is composed of a cobalt(II) ion, a pyridine-2,3-dicarboxylate dianion and two water molecules. The polymer has a zigzag structure consisting of a chain of edge-fused rings, and the polymer chains are linked by O-H.O hydrogen bonds into a three-dimensional framework.

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