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A head-to-head isomer of di-mu-pivalamidato-kappa4N,O-bis[(1,10-phenanthroline-kappa2N,N')platinum(II)] dinitrate dihydrate. 2003

Ken Sakai, and Mai Kurashima, and Norinobu Akiyama, and Naoki Satoh, and Takashi Kajiwara, and Tasuku Ito
Department of Applied Chemistry, Faculty of Science, Tokyo University of Science, Kagurazaka 1-3, Shinjuku-ku, Tokyo 162-8601, Japan. ksakai@rs.kagu.tus.ac.jp

In the title compound, [Pt(2)(C(5)H(10)NO)(2)(C(12)H(8)N(2))(2)](NO(3))(2)*-2H(2)O, the intradimer Pt-Pt distance is relatively short [2.8489 (17) A], which must be due to the strong intramolecular pi-pi-stacking interactions between the phenanthroline moieties. The dimers stack along the c axis, forming one-dimensional columns in which very intriguing d-d, pi-pi and d-pi interactions exist. Although the dimer-dimer Pt...Pt distances are very long [4.340 (2) and 4.231 (2) A], some short interdimer Pt...C contacts leading to strong interdimer associations are found [3.325 (19) and 3.402 (19) A].

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