Biomaterial Database

[Simultaneous spectrophotometric determination of trace ferrum and cobalt with 5-Br-PADAP and Tween-80]. 2000

Siqin, and C Jia, and Saiyinna, and M Hai

Department of Chemistry, Inner Mongolia Normal University, 010022 Hohhot.

A new simultaneous method for the determination of ferrum and cobalt with 5-Br-PADAP by spectrophotometry in the presence of Twen-80 is studied. The results showed that in pH = 3.4 HAc-NaAc buffer medium, ferrum and cobalt can formed colored complexes with 5-Br-PADAP. Its maximum absorption wavelengths are at 585 nm. Beer's law is obeyed for the concentration of ferrum in the range of 0-10 micrograms.25 mL-1 and 0-12 micrograms.25 mL-1 of cobalt. The apparent molar absorptivities are epsilon 585Fe = 7.18 x 10(4) and epsilon 585Co = 9.27 x 10(4) respectively. This method has been applied to the determination of ferrum and cobalt in water sample with satisfactory results.

UI	MeSH Term	Description	Entries
D007501	Iron	A metallic element with atomic symbol Fe, atomic number 26, and atomic weight 55.85. It is an essential constituent of HEMOGLOBINS; CYTOCHROMES; and IRON-BINDING PROTEINS. It plays a role in cellular redox reactions and in the transport of OXYGEN.	Iron-56,Iron 56
D011136	Polysorbates	Sorbitan mono-9-octadecanoate poly(oxy-1,2-ethanediyl) derivatives; complex mixtures of polyoxyethylene ethers used as emulsifiers or dispersing agents in pharmaceuticals.	Polysorbate,Polysorbate 20,Polysorbate 80,Sorbitan Derivatives,Tween,Tweens,PSML,Polyoxyethylene Sorbitan Monolaurate,Tween 20,Tween 60,Tween 80,Tween 81,Tween 85,20s, Polysorbate,20s, Tween,60s, Tween,80s, Polysorbate,80s, Tween,81s, Tween,85s, Tween,Derivative, Sorbitan,Derivatives, Sorbitan,Monolaurate, Polyoxyethylene Sorbitan,Monolaurates, Polyoxyethylene Sorbitan,PSMLs,Polyoxyethylene Sorbitan Monolaurates,Polysorbate 20s,Polysorbate 80s,Sorbitan Derivative,Sorbitan Monolaurate, Polyoxyethylene,Sorbitan Monolaurates, Polyoxyethylene,Tween 20s,Tween 60s,Tween 80s,Tween 81s,Tween 85s
D003035	Cobalt	A trace element that is a component of vitamin B12. It has the atomic symbol Co, atomic number 27, and atomic weight 58.93. It is used in nuclear weapons, alloys, and pigments. Deficiency in animals leads to anemia; its excess in humans can lead to erythrocytosis.	Cobalt-59,Cobalt 59
D001391	Azo Compounds	Organic chemicals where aryl or alkyl groups are joined by two nitrogen atoms through a double bond (R-N	Azo Dye,Azo Dyes,Compounds, Azo,Dye, Azo,Dyes, Azo
D013053	Spectrophotometry	The art or process of comparing photometrically the relative intensities of the light in different parts of the spectrum.