Solid-state electroluminescent devices based on transition metal complexes. 2003

Jason Slinker, and Dan Bernards, and Paul L Houston, and Héctor D Abruña, and Stefan Bernhard, and George G Malliaras
Department of Materials Science and Engineering, Cornell University, Ithaca, NY 14853, USA.

Transition metal complexes have emerged as promising candidates for applications in solid-state electroluminescent devices. These materials serve as multifunctional chromophores, into which electrons and holes can be injected, migrate and recombine to produce light emission. Their device characteristics are dominated by the presence of mobile ions that redistribute under an applied field and assist charge injection. As a result, an efficiency of 10 lm/W--among the highest efficiencies reported in a single layer electroluminescent device--was recently demonstrated. In this article we review the history of electroluminescence in transition metal complexes and discuss the issues that need to be addressed for these materials to succeed in display and lighting applications.

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