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Application of phosphine-oxazoline ligands in Ir-catalyzed asymmetric hydrogenation of acyclic aromatic N-arylimines. 2004
Department of Chemistry, Organic Chemistry, Uppsala University, Box 599, SE-75124 Uppsala, Sweden.
[reaction: see text] A new class of chiral phosphine-oxazoline ligands have been developed. Chiral Ir complexes prepared from these ligands induced high enantioselectivities (66-90% ee) when applied to the asymmetric hydrogenation of acyclic aromatic N-arylimines.
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