Proton transfer and N(+)-H...S(-) hydrogen bonds in the crystal structure of 4-aminothiophenol. 2004

Ram K R Jetti, and Roland Boese, and Tejender S Thakur, and Venu R Vangala, and Gautam R Desiraju
Institut für Anorganische Chemie, Universität Duisburg-Essen, Germany.

4-Aminothiophenol exists as 4-ammonio-1-benzenethiolate in the solid and liquid state. The crystal structure is characterised by a tetrahedral beta-As type network which is the driving force for the proton transfer.

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