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Diastereoselective reductive imino-aldol reaction of alpha-imino esters promoted by titanium tetraiodide: synthesis of alpha,beta-diamino esters. 2005
Department of Chemistry for Materials, Mie University, Tsu, Mie 514-8507, Japan. mshimizu@chem.mie-u.ac.jp
Under the influence of titanium tetraiodide reductive imino-aldol reaction of the N-tosylimine derived from ethyl glyoxylate proceeded with aldimines to give alpha,beta-diamino esters in good yields in a highly diastereoselective manner.
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