Biomaterial Database

Sulfinylcalix[4]arene-impregnated amberlite XAD-7 resin for the separation of niobium(V) from tantalum(V). 2005

Hiroaki Matsumiya, and Shizu Yasuno, and Nobuhiko Iki, and Sotaro Miyano

Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, Aramaki-Aoba 07, Aoba-ku, Sendai 980-8579, Japan. h-matsu@numse.nagoya-u.ac.jp

Amberlite XAD-7 resin was impregnated with p-tert-butylsulfinylcalix[4]arene. Niobium(V) was collected on the impregnated resin in yields of more than 90% around pH 5.4, whereas tantalum(V) was negligibly collected. The collected niobium(V) was desorbed with 9 M sulfuric acid nearly quantitatively, hence the separation of niobium(V) from tantalum(V) was successfully achieved.

UI	MeSH Term	Description	Entries
D009556	Niobium	A metal element atomic number 41, atomic weight 92.906, symbol Nb.	Niobium-93,Niobium 93
D010636	Phenols	Benzene derivatives that include one or more hydroxyl groups attached to the ring structure.
D011137	Polystyrenes	Polymerized forms of styrene used as a biocompatible material, especially in dentistry. They are thermoplastic and are used as insulators, for injection molding and casting, as sheets, plates, rods, rigid forms and beads.	Polystyrol,Polystyrene,Polystyrols
D002852	Chromatography, Ion Exchange	Separation technique in which the stationary phase consists of ion exchange resins. The resins contain loosely held small ions that easily exchange places with other small ions of like charge present in solutions washed over the resins.	Chromatography, Ion-Exchange,Ion-Exchange Chromatography,Chromatographies, Ion Exchange,Chromatographies, Ion-Exchange,Ion Exchange Chromatographies,Ion Exchange Chromatography,Ion-Exchange Chromatographies
D000180	Acrylic Resins	Polymers of high molecular weight which are derived from acrylic acid, methacrylic acid or other related compounds and are capable of being molded and then hardened to form useful components.	Acrylic Resin,Resin, Acrylic,Resins, Acrylic
D013440	Sulfides	Chemical groups containing the covalent sulfur bonds -S-. The sulfur atom can be bound to inorganic or organic moieties.	Sulfide,Thioether,Thioethers,Sulfur Ethers,Ethers, Sulfur
D013635	Tantalum	A rare metallic element, atomic number 73, atomic weight 180.948, symbol Ta. It is a noncorrosive and malleable metal that has been used for plates or disks to replace cranial defects, for wire sutures, and for making prosthetic devices.	Tantalum-181,Tantalum 181