Transformation of Dibenzo-p-Dioxin by Pseudomonas sp. Strain HH69. 1990

H Harms, and R M Wittich, and V Sinnwell, and H Meyer, and P Fortnagel, and W Francke
Institut für Allgemeine Botanik, Abteilung Mikrobiologie, Ohnhorststrasse 18, and Institut für Organische Chemie, Martin-Luther-King-Platz 4, Universität Hamburg, D-2000 Hamburg, Federal Republic of Germany.

Dibenzo-p-dioxin was oxidatively cleaved by the dibenzofuran-degrading bacterium Pseudomonas sp. strain HH69 to produce minor amounts of 1-hydroxydibenzo-p-dioxin and catechol, while a 2-phenoxy derivative of muconic acid was formed as the major product. Upon acidic methylation, the latter yielded the dimethylester of cis, trans-2-(2-hydroxyphenoxy)-muconic acid.

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