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Substituted alpha-(phenylhydrazono)phenylacetonitrile derivatives. Part 2: Synthesis and biological activity of pro-pesticides. 2006
Thomas Flury, and
Roger G Hall, and
Friedrich Karrer, and
Heinz Kienast, and
Katrin Leuenberger, and
Alfons Pascual, and
Alfred Rindlisbacher, and
Stephan Trah, and
Hans-Joerg Widmer
Syngenta Crop Protection AG, CH-4002 Basel, Switzerland.
Pro-pesticides of alpha-(2,6-dichloro-4-trifluoromethylphenylhydrazono)-4-nitrophenylacetonitrile have been prepared and tested against mite and insect pests. Variations in potency and spectrum were observed depending on the choice of cleavable pro-moiety. Cleavage of the pro-moiety was demonstrated in one case by measuring the rate of increase in the uncoupling activity using a mitochondrial preparation. Irradiation experiments have demonstrated a rapid isomerisation of the planar Z isomer to the E isomer, which is reversible.
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