-transparent.png){kind=logo}
A surprisingly stable S-nitrosothiol complex. 2006
Departamento de Química Inorgánica, Analítica y Química Física/INQUIMAE-CONICET, Facultad de Ciencias Exactas y Naturales, Universidad de Buenos Aires, Ciudad Universitaria, Pabellón II, Argentina.
In this work we present for the first time an X-ray structure of a coordinated S-nitrosothiol obtained by reaction of the extremely reactive K[IrCl5NO] with benzylmercaptan in acetonitrile. This surprisingly stable compound, trans-K[IrCl4(CH3CN)N(O)SCH2Ph], was isolated in high yield (80%) and fully characterized by FTIR, 1H NMR, and ESI-MS. To our knowledge this is the first example of a coordinated S-nitrosothiol that has been isolated.
| UI | MeSH Term | Description | Entries |
|---|
Related Publications
Laura L Perissinotti, and
Darío A Estrin, and
Gregory Leitus, and
Fabio Doctorovich
January 1996,
Methods in enzymology,
Laura L Perissinotti, and
Darío A Estrin, and
Gregory Leitus, and
Fabio Doctorovich
January 2005,
Methods in enzymology,
Laura L Perissinotti, and
Darío A Estrin, and
Gregory Leitus, and
Fabio Doctorovich
October 2001,
Journal of the American Chemical Society,
Laura L Perissinotti, and
Darío A Estrin, and
Gregory Leitus, and
Fabio Doctorovich
August 2009,
American journal of respiratory and critical care medicine,
Laura L Perissinotti, and
Darío A Estrin, and
Gregory Leitus, and
Fabio Doctorovich
December 2016,
Polymer chemistry,
Laura L Perissinotti, and
Darío A Estrin, and
Gregory Leitus, and
Fabio Doctorovich
January 2002,
Chemistry (Weinheim an der Bergstrasse, Germany),
Laura L Perissinotti, and
Darío A Estrin, and
Gregory Leitus, and
Fabio Doctorovich
December 2020,
Nature chemistry,
Laura L Perissinotti, and
Darío A Estrin, and
Gregory Leitus, and
Fabio Doctorovich
June 2006,
American journal of respiratory and critical care medicine,
Laura L Perissinotti, and
Darío A Estrin, and
Gregory Leitus, and
Fabio Doctorovich
May 2007,
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences,
Laura L Perissinotti, and
Darío A Estrin, and
Gregory Leitus, and
Fabio Doctorovich
May 2003,
Brazilian journal of medical and biological research = Revista brasileira de pesquisas medicas e biologicas,
