Direct palladium-catalyzed ortho-arylation of benzylamines. 2006

Anna Lazareva, and Olafs Daugulis
Department of Chemistry, University of Houston, Houston, Texas 77204, USA.

[Structure: see text] Unsubstituted benzylamines and N-methylbenzylamine can be ortho-arylated under palladium catalysis at 130 degrees C. The reactions require the presence of trifluoroacetic acid and silver acetate.

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