BIOMAT Database Logo BIOMAT Database Logo

Synthesis and structural characterisation of the first N-heterocyclic carbene ligand fused to a porphyrin. 2007

Sébastien Richeter, and Aurélie Hadj-Aïssa, and Céline Taffin, and Arie van der Lee, and Dominique Leclercq
Institut Charles Gerhardt, UM2, CNRS, équipe CMOS, CC 007, Université Montpellier 2, Place Eugène Bataillon, 34095, Montpellier Cedex 05, France. Sebastien.Richeter@univ-montp2.fr

The functionalisation of two neighboring beta-pyrrolic positions of a porphyrin by a fused N-heterocyclic carbene ligand, the subsequent metallation of this external coordination site by palladium(II) and the structural characterisation of the resulting compounds are presented.

UI MeSH Term Description Entries
D008024 Ligands A molecule that binds to another molecule, used especially to refer to a small molecule that binds specifically to a larger molecule, e.g., an antigen binding to an antibody, a hormone or neurotransmitter binding to a receptor, or a substrate or allosteric effector binding to an enzyme. Ligands are also molecules that donate or accept a pair of electrons to form a coordinate covalent bond with the central metal atom of a coordination complex. (From Dorland, 27th ed) Ligand
D008697 Methane The simplest saturated hydrocarbon. It is a colorless, flammable gas, slightly soluble in water. It is one of the chief constituents of natural gas and is formed in the decomposition of organic matter. (Grant & Hackh's Chemical Dictionary, 5th ed)
D008958 Models, Molecular Models used experimentally or theoretically to study molecular shape, electronic properties, or interactions; includes analogous molecules, computer-generated graphics, and mechanical structures. Molecular Models,Model, Molecular,Molecular Model
D009584 Nitrogen An element with the atomic symbol N, atomic number 7, and atomic weight [14.00643; 14.00728]. Nitrogen exists as a diatomic gas and makes up about 78% of the earth's atmosphere by volume. It is a constituent of proteins and nucleic acids and found in all living cells.
D011166 Porphyrins A group of compounds containing the porphin structure, four pyrrole rings connected by methine bridges in a cyclic configuration to which a variety of side chains are attached. The nature of the side chain is indicated by a prefix, as uroporphyrin, hematoporphyrin, etc. The porphyrins, in combination with iron, form the heme component in biologically significant compounds such as hemoglobin and myoglobin. Porphyrin
D006571 Heterocyclic Compounds Cyclic compounds that include atoms other than carbon in their ring structure. Heterocyclic Compound,Compound, Heterocyclic,Compounds, Heterocyclic
D006838 Hydrocarbons Organic compounds that primarily contain carbon and hydrogen atoms with the carbon atoms forming a linear or circular structure. Hydrocarbon,Saturated Hydrocarbons,Unsaturated Hydrocarbons,Hydrocarbons, Saturated,Hydrocarbons, Unsaturated
D015394 Molecular Structure The location of the atoms, groups or ions relative to one another in a molecule, as well as the number, type and location of covalent bonds. Structure, Molecular,Molecular Structures,Structures, Molecular
D018360 Crystallography, X-Ray The study of crystal structure using X-RAY DIFFRACTION techniques. (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) X-Ray Crystallography,Crystallography, X Ray,Crystallography, Xray,X Ray Crystallography,Xray Crystallography,Crystallographies, X Ray,X Ray Crystallographies

Related Publications

Sébastien Richeter, and Aurélie Hadj-Aïssa, and Céline Taffin, and Arie van der Lee, and Dominique Leclercq
First imidazole-fused carbaporphyrinoid and its conversion to a N-heterocyclic carbene precursor.
April 2020, Chemical communications (Cambridge, England),
Sébastien Richeter, and Aurélie Hadj-Aïssa, and Céline Taffin, and Arie van der Lee, and Dominique Leclercq
First aryl-substituted acyclic imino-N-heterocyclic carbene ligand precursor: synthesis, characterisation and coordination with silver(I) and copper(I).
April 2010, Dalton transactions (Cambridge, England : 2003),
Sébastien Richeter, and Aurélie Hadj-Aïssa, and Céline Taffin, and Arie van der Lee, and Dominique Leclercq
A hybrid carbocyclic/N-heterocyclic carbene ligand.
February 2017, Chemical communications (Cambridge, England),
Sébastien Richeter, and Aurélie Hadj-Aïssa, and Céline Taffin, and Arie van der Lee, and Dominique Leclercq
Platinum(iv) N-heterocyclic carbene complexes: their synthesis, characterisation and cytotoxic activity.
July 2016, Dalton transactions (Cambridge, England : 2003),
Sébastien Richeter, and Aurélie Hadj-Aïssa, and Céline Taffin, and Arie van der Lee, and Dominique Leclercq
N-Heterocyclic Carbene-Catalyzed Enantioselective Synthesis of N-Fused Polycyclic Dihydropyrido[1,2-α]-indolones.
July 2023, Organic letters,
Sébastien Richeter, and Aurélie Hadj-Aïssa, and Céline Taffin, and Arie van der Lee, and Dominique Leclercq
Synthesis and characterisation of anionic and neutral gallium(I) N-heterocyclic carbene analogues.
August 2012, Dalton transactions (Cambridge, England : 2003),
Sébastien Richeter, and Aurélie Hadj-Aïssa, and Céline Taffin, and Arie van der Lee, and Dominique Leclercq
Synthesis, structural characterisation and stereochemical investigation of chiral sulfur-functionalised N-heterocyclic carbene complexes of palladium and platinum.
April 2013, Chemistry (Weinheim an der Bergstrasse, Germany),
Sébastien Richeter, and Aurélie Hadj-Aïssa, and Céline Taffin, and Arie van der Lee, and Dominique Leclercq
Synthesis and structural characterization of ruthenium carbonyl cluster complexes containing platinum with a bulky N-heterocyclic carbene ligand.
January 2014, Inorganic chemistry,
Sébastien Richeter, and Aurélie Hadj-Aïssa, and Céline Taffin, and Arie van der Lee, and Dominique Leclercq
Synthesis and characterisation of an N-heterocyclic carbene with spatially-defined steric impact.
August 2016, Dalton transactions (Cambridge, England : 2003),
Sébastien Richeter, and Aurélie Hadj-Aïssa, and Céline Taffin, and Arie van der Lee, and Dominique Leclercq
N-heterocyclic carbene embedded in an N-confused porphyrin framework.
September 2010, Inorganic chemistry,
Copied contents to your clipboard!