Unprecedented optically induced long-lived intramolecular electron transfer in cobalt-dioxolene complexes. 2007

Alessandra Beni, and Andrea Dei, and Mario Rizzitano, and Lorenzo Sorace
INSTM Research Unit and Dipartimento di Chimica Università di Firenze, Via della Lastruccia 3, 50019, Sesto Fiorentino, Firenze, Italy.

The observation of very long lifetimes of the metastable states of two cobalt-dioxolene complexes undergoing photoinduced and high T(c) thermally-induced valence tautomer interconversion opens new research perspectives.

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