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Simple preparation of diamondoid 1,3-dienes via oxetane ring opening. 2007
Andrey A Fokin, and
Ekaterina D Butova, and
Lesya V Chernish, and
Natalie A Fokina, and
Jeremy E P Dahl, and
Robert M K Carlson, and
Peter R Schreiner
Department of Organic Chemistry, Kiev Polytechnic Institute, pr. Pobedy 37, 03056 Kiev, Ukraine. aaf@xtf.ntu-kpi.kiev.ua
The transformations of apical mono- and bisacetyl diamondoids to the respective oxetanes and subsequent acid-catalyzed ring opening/dehydration lead to diamondoidyl mono- and bis-1,3-dienes in high preparative yields.
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