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A mild Cu(I)-catalyzed regioselective diamination of conjugated dienes. 2007

Weicheng Yuan, and Haifeng Du, and Baoguo Zhao, and Yian Shi
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.

This paper describes a novel diamination process that uses CuCl as catalyst and di-tert-butyldiaziridinone as nitrogen source. A wide variety of conjugated dienes and a triene can be effectively diaminated in good yields with generally high regioselectivity under mild reaction conditions.

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