Directed electroless growth of metal nanostructures on patterned self-assembled monolayers. 2007

Jayne C Garno, and Christopher D Zangmeister, and James D Batteas
Chemical Sciences and Technology Laboratory, National Institute of Standards and Technology, 100 Bureau Drive, Gaithersburg, Maryland 20899, USA.

The directed placement of Cu nanostructures on surfaces has been studied using a combination of scanning probe lithography and electroless metal deposition onto nanopatterned SAMs of 16-mercaptohexadecanoic acid (16-MHA) on Au. In situ studies using nanoscale molecular gradients reveal how controlling the areal density of the 16-MHA molecules dictates the nucleation and growth of the metal nanostructures. The influence of controlling pattern line spacing and tip path on pattern feature fidelity is also discussed.

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