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Gold nanoparticle-based monitoring of the reduction of oxidized to reduced glutathione. 2007
Xiaorong He, and
Zhifeng Zhong, and
Yanbing Guo, and
Jing Lv, and
Jialiang Xu, and
Mei Zhu, and
Yuliang Li, and
Huibiao Liu, and
Shu Wang, and
Yulan Zhu, and
Daoben Zhu
Key Laboratory of Organic Solids, Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beiijng 100080, P. R. China.
We demonstrate the reduction of oxidized to reduced glutathione in the presence of glutathione reductase enzyme based on the modulation in photoluminescent quenching efficiency between the perylene bisimide chromophore TPPCA and gold nanoparticles (AuNPs). The TPPCA-AuNPs assembly shows a turn-on fluorescent signal in the presence of reduced glutathione, which provides a new concept to measure the balance of glutathione in a creature.
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