Biomaterial Database

Estimation of the bioaccessible arsenic fraction in soils using near infrared spectroscopy. 2007

Mark Cave, and Helen Taylor, and Joanna Wragg

British Geological Survey, Keyworth, Nottingham, UK. mrca@bgs.ac.uk

A self-modelling mixture algorithm was used to convert raw NIR spectra of soils, developed over Jurassic ironstones, into five underlying spectral components (SC) and associated coefficients. The five SCs were shown to be significantly correlated to the total As, bioaccessible As and total Fe contents of the soils and tentatively assigned to crystalline Fe oxides, Fe oxyhydroxides and clay components in the soils. A linear regression model, using the SC coefficients associated with the clay fraction, the Fe oxyhydroxides and the total As content of the soils as independent variables, was shown to predict the bioaccessible As content of the soils (as measured by an in vitro laboratory test) with a 95% confidence limit of +/-1.8 mg kg(-1) and a median R2 value of 0.80. The approach could be extended to other soil types but the model presented here only applies to the Jurassic ironstone soils from Lincolnshire UK.

UI	MeSH Term	Description	Entries
D008954	Models, Biological	Theoretical representations that simulate the behavior or activity of biological processes or diseases. For disease models in living animals, DISEASE MODELS, ANIMAL is available. Biological models include the use of mathematical equations, computers, and other electronic equipment.	Biological Model,Biological Models,Model, Biological,Models, Biologic,Biologic Model,Biologic Models,Model, Biologic
D004784	Environmental Monitoring	The monitoring of the level of toxins, chemical pollutants, microbial contaminants, or other harmful substances in the environment (soil, air, and water), workplace, or in the bodies of people and animals present in that environment.	Monitoring, Environmental,Environmental Surveillance,Surveillance, Environmental
D006113	United Kingdom	Country in northwestern Europe including Great Britain and the northern one-sixth of the island of Ireland, located between the North Sea and north Atlantic Ocean. The capital is London.	Great Britain,Isle of Man
D006801	Humans	Members of the species Homo sapiens.	Homo sapiens,Man (Taxonomy),Human,Man, Modern,Modern Man
D000465	Algorithms	A procedure consisting of a sequence of algebraic formulas and/or logical steps to calculate or determine a given task.	Algorithm
D001151	Arsenic	A shiny gray element with atomic symbol As, atomic number 33, and atomic weight 75. It occurs throughout the universe, mostly in the form of metallic arsenides. Most forms are toxic. According to the Fourth Annual Report on Carcinogens (NTP 85-002, 1985), arsenic and certain arsenic compounds have been listed as known carcinogens. (From Merck Index, 11th ed)	Arsenic-75,Arsenic 75
D001682	Biological Availability	The extent to which the active ingredient of a drug dosage form becomes available at the site of drug action or in a biological medium believed to reflect accessibility to a site of action.	Availability Equivalency,Bioavailability,Physiologic Availability,Availability, Biologic,Availability, Biological,Availability, Physiologic,Biologic Availability,Availabilities, Biologic,Availabilities, Biological,Availabilities, Physiologic,Availability Equivalencies,Bioavailabilities,Biologic Availabilities,Biological Availabilities,Equivalencies, Availability,Equivalency, Availability,Physiologic Availabilities
D012987	Soil	The unconsolidated mineral or organic matter on the surface of the earth that serves as a natural medium for the growth of land plants.	Peat,Humus,Soils
D012989	Soil Pollutants	Substances which pollute the soil. Use for soil pollutants in general or for which there is no specific heading.	Soil Pollutant,Pollutant, Soil,Pollutants, Soil
D016014	Linear Models	Statistical models in which the value of a parameter for a given value of a factor is assumed to be equal to a + bx, where a and b are constants. The models predict a linear regression.	Linear Regression,Log-Linear Models,Models, Linear,Linear Model,Linear Regressions,Log Linear Models,Log-Linear Model,Model, Linear,Model, Log-Linear,Models, Log-Linear,Regression, Linear,Regressions, Linear