BIOMAT Database Logo BIOMAT Database Logo

Efficient synthesis of open-cage fullerene derivatives having 16-membered-ring orifices. 2007

Manolis M Roubelakis, and Yasujiro Murata, and Koichi Komatsu, and Michael Orfanopoulos
Department of Chemistry, University of Crete, Voutes 71003 Heraklion, Crete, Greece.

The synthesis of 10 new open-cage fullerene derivatives with a 16-membered-ring orifice is being reported. These compounds, derived from the regioselective addition reaction of an aromatic hydrazine or hydrazone to isomeric diketone derivatives of C(60), were isolated in moderate to excellent yields.

UI MeSH Term Description Entries

Related Publications

Manolis M Roubelakis, and Yasujiro Murata, and Koichi Komatsu, and Michael Orfanopoulos
Open-cage fullerene derivatives with 15-membered-ring orifices.
June 2004, The Journal of organic chemistry,
Manolis M Roubelakis, and Yasujiro Murata, and Koichi Komatsu, and Michael Orfanopoulos
Open-cage fullerene derivatives having 11-, 12-, and 13-membered-ring orifices: chemical transformations of the organic addends on the rim of the orifice.
August 2007, The Journal of organic chemistry,
Manolis M Roubelakis, and Yasujiro Murata, and Koichi Komatsu, and Michael Orfanopoulos
Synthesis of open-cage ketolactam derivatives of fullerene C60 encapsulating a hydrogen molecule.
June 2014, Organic letters,
Manolis M Roubelakis, and Yasujiro Murata, and Koichi Komatsu, and Michael Orfanopoulos
Synthesis of a Dihydroxylated Open-Cage [70]Fullerene by a Reductive Ring-Closure Reaction.
November 2020, Organic letters,
Manolis M Roubelakis, and Yasujiro Murata, and Koichi Komatsu, and Michael Orfanopoulos
Synthesis of stable derivatives of c(62): the first nonclassical fullerene incorporating a four-membered ring.
February 2003, Journal of the American Chemical Society,
Manolis M Roubelakis, and Yasujiro Murata, and Koichi Komatsu, and Michael Orfanopoulos
Isolation of two seven-membered ring C58 fullerene derivatives: C58F17CF3 and C58F18.
July 2005, Science (New York, N.Y.),
Manolis M Roubelakis, and Yasujiro Murata, and Koichi Komatsu, and Michael Orfanopoulos
Synthesis of 18-membered open-cage fullerenes through controlled stepwise fullerene skeleton bond cleavage processes and substituent-mediated tuning of the redox potential of open-cage fullerenes.
December 2011, The Journal of organic chemistry,
Manolis M Roubelakis, and Yasujiro Murata, and Koichi Komatsu, and Michael Orfanopoulos
Novel open-cage fullerenes having a 12-membered-ring orifice: removal of the organic addends from the rim of the orifice.
April 2004, Organic letters,
Manolis M Roubelakis, and Yasujiro Murata, and Koichi Komatsu, and Michael Orfanopoulos
Open-cage fullerene derivatives suitable for the encapsulation of a hydrogen molecule.
June 2005, The Journal of organic chemistry,
Manolis M Roubelakis, and Yasujiro Murata, and Koichi Komatsu, and Michael Orfanopoulos
Synthesis and characterisation of an open-cage fullerene encapsulating hydrogen fluoride.
March 2015, Chemical communications (Cambridge, England),
Copied contents to your clipboard!