Ternary cubic phases containing ionic liquid. 2008

Zhongni Wang, and Wu Zhou, and Ganzuo Li
College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014, China. zhongniw@hotmail.com

The phase diagram of 1-butyl-3-methylimidazolium tetrafluoroborate (bmim-BF(4)) in aqueous solutions of oleyl polyoxyethylene (20) ether (C(18:1)E(20)) was determined at 25 degrees C by a combination of visual inspection and small-angle X-ray scattering (SAXS). The micellar cubic Im3m liquid crystalline phase found in the ternary system was investigated by means of SAXS and rheological techniques. The cubic samples show highly elastic gel-like properties indicated by their mechanical and discrete relaxation spectra. Moreover at a constant C(18:1)E(20)/bmim-BF(4) ratio, with decreasing water content the network strength increases. The internal structure apparently becomes more stable, as indicated by an increase in the storage and loss moduli and a decrease in the lattice parameter alpha and interfacial area of per surfactant a(S). Furthermore, investigations on the representative micellar Im3m cubic phases formed in a relatively hydrophobic ionic liquid bmim-PF(6) with C(18:1)E(20) and water ternary system (P(1)), a C(18:1)E(20)/water binary system (J(1)), and C(18:1)E(20)/water/bmim-BF(4) system (B(1)) were made in comparison. It can be clearly seen that appreciably different mechanical spectra and relaxation spectra are shown by the cubic phases investigated. B(1) exhibits a typical gel-like dynamic rheogram while P(1) exhibits fluid-like viscoelastic properties to some extent, and J(1) shows traits of the general Maxwell model. These differences are analyzed through SAXS data as the employment of ionic liquids and their different location in the cubic phases.

UI MeSH Term Description Entries

Related Publications

Zhongni Wang, and Wu Zhou, and Ganzuo Li
December 2009, European biophysics journal : EBJ,
Zhongni Wang, and Wu Zhou, and Ganzuo Li
July 2012, Chemical communications (Cambridge, England),
Zhongni Wang, and Wu Zhou, and Ganzuo Li
August 2004, Colloids and surfaces. B, Biointerfaces,
Zhongni Wang, and Wu Zhou, and Ganzuo Li
May 1999, Physical review. E, Statistical physics, plasmas, fluids, and related interdisciplinary topics,
Zhongni Wang, and Wu Zhou, and Ganzuo Li
May 2005, Langmuir : the ACS journal of surfaces and colloids,
Zhongni Wang, and Wu Zhou, and Ganzuo Li
November 2017, Journal of physics. Condensed matter : an Institute of Physics journal,
Zhongni Wang, and Wu Zhou, and Ganzuo Li
August 2006, Journal of the American Chemical Society,
Zhongni Wang, and Wu Zhou, and Ganzuo Li
April 2020, Langmuir : the ACS journal of surfaces and colloids,
Zhongni Wang, and Wu Zhou, and Ganzuo Li
December 2004, Chemical communications (Cambridge, England),
Zhongni Wang, and Wu Zhou, and Ganzuo Li
November 2017, Journal of AOAC International,
Copied contents to your clipboard!