Spectroscopic studies of zinc(II)tetraphenylporphyrin molecular complex with 1,4-dioxane. 2008

N Sh Lebedeva, and A I Karelin, and N A Pavlycheva, and W Zielenkiewicz, and R Swierzewski
Institute of Solution Chemistry of Russian Academy of Sciences, 1 Akademicheskaya Street, Ivanovo 153045, Russian Federation. nsl@isc-ras.ru

The molecular complex of zinc(II)tetraphenylporphyrin with 1,4-dioxane has been obtained. The IR spectra of the [Zn(TPhP)(1,4-dioxane)2] stabile molecular complex between 4000 and 50cm(-1) have been studied. An interpretation is given on the base the "chair" conformation of 1,4-dioxane molecule.

UI MeSH Term Description Entries
D008665 Metalloporphyrins Porphyrins which are combined with a metal ion. The metal is bound equally to all four nitrogen atoms of the pyrrole rings. They possess characteristic absorption spectra which can be utilized for identification or quantitative estimation of porphyrins and porphyrin-bound compounds. Metalloporphyrin
D004146 Dioxanes Compounds that contain the structure 1,4-dioxane.
D013055 Spectrophotometry, Infrared Spectrophotometry in the infrared region, usually for the purpose of chemical analysis through measurement of absorption spectra associated with rotational and vibrational energy levels of molecules. (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) IR Spectra,Infrared Spectrophotometry,IR Spectras,Spectra, IR
D015394 Molecular Structure The location of the atoms, groups or ions relative to one another in a molecule, as well as the number, type and location of covalent bonds. Structure, Molecular,Molecular Structures,Structures, Molecular

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