[Influence of nanosized TiO2 catalyzed ozonation on the ammonia concentration in Songhua River water]. 2007

Sheng-Jun Wang, and Jun Ma, and Yi-Xin Yang, and Jing Zhang, and Qing-Dong Qin, and Tao Liang
School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China. wangsj80@126.com

Changes of the ammonia concentration in Songhua River water treatment using catalyzed ozonation were investigated. Nanosized TiO2 loaded on haydite, silica-gel and zeolite was prepared as the catalyst. The ammonia concentration increased in the first stage, then decreased. After 30 min reaction, the ultimate concentration was close to the initial concentration in ozonation. In catalyzed ozonation which used TiO2/ haydite or TiO2 /silica-gel as the catalyst, the ammonia concentration also increased primarily and then decreased, but the average concentration was higher than that in ozonation alone. In catalyzed ozonation which used TiO2/zeolite as the catalyst, the ammonia concentration decreased primarily, then increased to a peak value, and decreased again. The removal efficiency was close to 80% after 30 min reaction. Effect of ozone dosage, catalyst dosage and temperature were investigated respectively. Increasing the ozone dosage, the maximum of the ammonia concentration appeared ahead and the average concentration of ammonia decreased either in ozonation or in catalyzed ozonation. Increasing the dosage of TiO2 /haydite or TiO2/silica-gel, the average concentration of ammonia increased. The removal efficiency of ammonia benefited from the increase of TiO2/zeolite dosage, but it was affected little when TiO2/zeolite dosage was above 50 g. When the temperature increased from 10 degrees C to 30 degrees C, the changes of ammonia concentration were not affected in catalyzed ozonation using TiO2/haydite or TiO2/silica-gel as the catalyst. While the increase of temperature yielded an increase of ammonia removal efficiency when using TiO2/zeolite as the catalyst.

UI MeSH Term Description Entries
D010084 Oxidation-Reduction A chemical reaction in which an electron is transferred from one molecule to another. The electron-donating molecule is the reducing agent or reductant; the electron-accepting molecule is the oxidizing agent or oxidant. Reducing and oxidizing agents function as conjugate reductant-oxidant pairs or redox pairs (Lehninger, Principles of Biochemistry, 1982, p471). Redox,Oxidation Reduction
D010126 Ozone The unstable triatomic form of oxygen, O3. It is a powerful oxidant that is produced for various chemical and industrial uses. Its production is also catalyzed in the ATMOSPHERE by ULTRAVIOLET RAY irradiation of oxygen or other ozone precursors such as VOLATILE ORGANIC COMPOUNDS and NITROGEN OXIDES. About 90% of the ozone in the atmosphere exists in the stratosphere (STRATOSPHERIC OZONE). Ground Level Ozone,Low Level Ozone,Tropospheric Ozone,Level Ozone, Ground,Level Ozone, Low,Ozone, Ground Level,Ozone, Low Level,Ozone, Tropospheric
D002384 Catalysis The facilitation of a chemical reaction by material (catalyst) that is not consumed by the reaction. Catalyses
D002681 China A country spanning from central Asia to the Pacific Ocean. Inner Mongolia,Manchuria,People's Republic of China,Sinkiang,Mainland China
D005618 Fresh Water Water containing no significant amounts of salts, such as water from RIVERS and LAKES. Freshwater,Fresh Waters,Freshwaters,Water, Fresh,Waters, Fresh
D000641 Ammonia A colorless alkaline gas. It is formed in the body during decomposition of organic materials during a large number of metabolically important reactions. Note that the aqueous form of ammonia is referred to as AMMONIUM HYDROXIDE.
D014025 Titanium A dark-gray, metallic element of widespread distribution but occurring in small amounts with atomic number, 22, atomic weight, 47.867 and symbol, Ti; specific gravity, 4.5; used for fixation of fractures.
D014874 Water Pollutants, Chemical Chemical compounds which pollute the water of rivers, streams, lakes, the sea, reservoirs, or other bodies of water. Chemical Water Pollutants,Landfill Leachate,Leachate, Landfill,Pollutants, Chemical Water
D014876 Water Pollution Contamination of bodies of water (such as LAKES; RIVERS; SEAS; and GROUNDWATER.) Thermal Water Pollution,Water Pollution, Thermal,Pollution, Thermal Water,Pollution, Water,Pollutions, Thermal Water,Pollutions, Water,Thermal Water Pollutions,Water Pollutions,Water Pollutions, Thermal
D017641 Zeolites Zeolites. A group of crystalline, hydrated alkali-aluminum silicates. They occur naturally in sedimentary and volcanic rocks, altered basalts, ores, and clay deposits. Some 40 known zeolite minerals and a great number of synthetic zeolites are available commercially. (From Merck Index, 11th ed) Zeolite

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