From ionic liquid to electrolyte solution: dynamics of 1-N-butyl-3-N-methylimidazolium tetrafluoroborate/dichloromethane mixtures. 2008

Johannes Hunger, and Alexander Stoppa, and Richard Buchner, and Glenn Hefter
Institut für Physikalische und Theoretische Chemie, Universität Regensburg, Regensburg, Germany.

Dielectric spectra have been measured at 25 degrees C for mixtures of the room temperature ionic liquid 1- N-butyl-3- N-methylimidazolium tetrafluoroborate (IL) with dichloromethane (DCM) over the entire composition range at frequencies 0.2 less than or approximately nu/GHz < or = 89. The spectra could be satisfactorily fitted by assuming only two relaxation modes: a Cole-Cole process at lower frequencies and a Debye process at higher frequencies. However, detailed analysis indicated that both spectral features contain additional modes, which could not be resolved due to overlaps. The spectra indicate that the IL appears to retain its chemical character to extraordinarily high levels of dilution ( x IL greater than or approximately 0.5) in DCM. At even higher dilutions ( x IL less than or approximately 0.3), the IL behaves as a conventional but strongly associated electrolyte.

UI MeSH Term Description Entries

Related Publications

Johannes Hunger, and Alexander Stoppa, and Richard Buchner, and Glenn Hefter
November 2011, Physical chemistry chemical physics : PCCP,
Johannes Hunger, and Alexander Stoppa, and Richard Buchner, and Glenn Hefter
May 2016, Langmuir : the ACS journal of surfaces and colloids,
Johannes Hunger, and Alexander Stoppa, and Richard Buchner, and Glenn Hefter
February 2014, The journal of physical chemistry. B,
Johannes Hunger, and Alexander Stoppa, and Richard Buchner, and Glenn Hefter
August 2005, The journal of physical chemistry. B,
Johannes Hunger, and Alexander Stoppa, and Richard Buchner, and Glenn Hefter
February 2012, The journal of physical chemistry. A,
Johannes Hunger, and Alexander Stoppa, and Richard Buchner, and Glenn Hefter
October 2014, Journal of chemical theory and computation,
Johannes Hunger, and Alexander Stoppa, and Richard Buchner, and Glenn Hefter
July 2006, Chemphyschem : a European journal of chemical physics and physical chemistry,
Johannes Hunger, and Alexander Stoppa, and Richard Buchner, and Glenn Hefter
January 2013, Microscopy research and technique,
Johannes Hunger, and Alexander Stoppa, and Richard Buchner, and Glenn Hefter
June 2012, Journal of nanoscience and nanotechnology,
Copied contents to your clipboard!