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Synthesis, crystal structure and magnetic properties of a mixed-valence pentanuclear cobalt complex. 2008
State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, People's Republic of China.
Solvothermal reaction of Co(OAc)2.4H2O with H4L (H4L = 2-((2-hydroxybenzylidene)amino)-2-hydroxymethylpropane-1,3-diol) in MeCN gave a mixed-valence pentanuclear cobalt complex [Co5(HL)2(H2L)2(OAc)2].2.5H2O. Crystal structural analysis revealed that two Co(III) ions were linked to a central triangular Co(II) core through HL(3-) and H2L(2-) hydroxyl groups. Magnetic measurements showed interesting magnetic properties that were assigned to spin-orbital coupling and ferromagnetic exchange interactions.
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