Knoop hardness depth profile of polyacid-modified composite resins. 2008

Nikolaos S Koupis, and Chris W J Vercruysse, and Luc C Martens, and Ronald M H Verbeeck
Department of Paediatric Dentistry, PaeCaMeD, School of Dentistry, Ghent University, Gent, Belgium.

OBJECTIVE To determine the hardness versus depth profile of several polyacid-modified composite resins (PAM-Cs) as a function of shade (A2, A4) and compare the depth of cure (DoC) based on these profiles with that previously obtained with the scraping and penetrometer methods. METHODS Samples of 6 PAM-Cs (Hytac, 3M ESPE; F2000, 3M ESPE; Glasiosite, Voco; Dyract, Dentsply DeTrey; Dyract AP, Dentsply DeTrey; Compoglass F, Vivadent) and 3 composite resins (Herculite Enamel XRV, Kerr; Z100, 3M ESPE; Durafill VS, Heraeus Kulzer) with shades A2 and A4 were light-cured in bulk in split stainless steel molds (thickness ranging from 0.5 to 3.5 mm in steps of 0.5 mm). The Knoop hardness of the irradiated top (KHN(surface)) and nonirradiated bottom (KHN(bottom)) surfaces was determined as a function of sample thickness using a microhardness tester. RESULTS Regression analysis demonstrated that for a given material, KHN(bottom) equals KHN(surface) up to a specific depth (= DoC) depending on the material and shade and then decreases linearly with increasing depth. The decrease of the KHN per unit depth differs significantly among materials and shades. According to a regression analysis, the scraping and penetrometer methods overestimate the DoC of PAM-Cs compared to the method based on the change of the hardness indentation with depth. CONCLUSIONS Shade A2 results in greater values of DoC than shade A4, the effect depending quantitatively on the formulation of the material. Some formulations of PAM-Cs do not reach a DoC of 2 mm, a layer recommended to be applied in the incremental technique. The DoC as determined according to ISO 4049:2000 apparently is based on a lower degree of polymerization corresponding to a KHN of 80% of the irradiated surface.

UI MeSH Term Description Entries
D008422 Materials Testing The testing of materials and devices, especially those used for PROSTHESES AND IMPLANTS; SUTURES; TISSUE ADHESIVES; etc., for hardness, strength, durability, safety, efficacy, and biocompatibility. Biocompatibility Testing,Biocompatible Materials Testing,Hemocompatibility Testing,Testing, Biocompatible Materials,Testing, Hemocompatible Materials,Hemocompatibility Testings,Hemocompatible Materials Testing,Materials Testing, Biocompatible,Materials Testing, Hemocompatible,Testing, Biocompatibility,Testing, Hemocompatibility,Testing, Materials,Testings, Biocompatibility
D012044 Regression Analysis Procedures for finding the mathematical function which best describes the relationship between a dependent variable and one or more independent variables. In linear regression (see LINEAR MODELS) the relationship is constrained to be a straight line and LEAST-SQUARES ANALYSIS is used to determine the best fit. In logistic regression (see LOGISTIC MODELS) the dependent variable is qualitative rather than continuously variable and LIKELIHOOD FUNCTIONS are used to find the best relationship. In multiple regression, the dependent variable is considered to depend on more than a single independent variable. Regression Diagnostics,Statistical Regression,Analysis, Regression,Analyses, Regression,Diagnostics, Regression,Regression Analyses,Regression, Statistical,Regressions, Statistical,Statistical Regressions
D003116 Color The visually perceived property of objects created by absorption or reflection of specific wavelengths of light. Colors
D003188 Composite Resins Synthetic resins, containing an inert filler, that are widely used in dentistry. Composite Resin,Resin, Composite,Resins, Composite
D003799 Dental Stress Analysis The description and measurement of the various factors that produce physical stress upon dental restorations, prostheses, or appliances, materials associated with them, or the natural oral structures. Analyses, Dental Stress,Analysis, Dental Stress,Stress Analyses, Dental,Stress Analysis, Dental,Dental Stress Analyses
D006244 Hardness The mechanical property of material that determines its resistance to force. HARDNESS TESTS measure this property. Hardnesses
D000704 Analysis of Variance A statistical technique that isolates and assesses the contributions of categorical independent variables to variation in the mean of a continuous dependent variable. ANOVA,Analysis, Variance,Variance Analysis,Analyses, Variance,Variance Analyses
D044367 Phase Transition A change of a substance from one form or state to another. Gas-Liquid-Solid Phase Transitions,Sol-Gel Phase Transition,Gas Liquid Solid Phase Transitions,Gas-Liquid-Solid Phase Transition,Phase Transition, Gas-Liquid-Solid,Phase Transition, Sol-Gel,Phase Transitions,Phase Transitions, Gas-Liquid-Solid,Phase Transitions, Sol-Gel,Sol Gel Phase Transition,Sol-Gel Phase Transitions,Transition, Gas-Liquid-Solid Phase,Transition, Sol-Gel Phase,Transitions, Gas-Liquid-Solid Phase,Transitions, Sol-Gel Phase
D055115 Light-Curing of Dental Adhesives The hardening or polymerization of bonding agents (DENTAL CEMENTS) via exposure to light. Dental Bonding, Light-Cured,Light-Curing of Dental Cements,Light-Curing of Dental Resins,Dental Adhesives Light-Curing,Dental Bonding, Light Cured,Dental Bondings, Light-Cured,Dental Cements Light-Curing,Dental Resins Light-Curings,Light Curing of Dental Adhesives,Light Curing of Dental Cements,Light Curing of Dental Resins,Light-Cured Dental Bonding,Light-Cured Dental Bondings
D020770 Compomers Composite materials composed of an ion-leachable glass embedded in a polymeric matrix. They differ from GLASS IONOMER CEMENTS in that partially silanized glass particles are used to provide a direct bond to the resin matrix and the matrix is primarily formed by a light-activated, radical polymerization reaction. Compomer,Composite Resins, Polyacid-Modified,Polyacid-Modified Composite Resin,Polyacid-Modified Composite Resins,Composite Resin, Polyacid-Modified,Composite Resins, Polyacid Modified,Polyacid Modified Composite Resin,Polyacid Modified Composite Resins,Resin, Polyacid-Modified Composite,Resins, Polyacid-Modified Composite

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