Physico-chemical properties of iodine-adsorbed single-walled carbon nanotubes. 2009

Chiharu Hayakawa, and Koki Urita, and Tomonori Ohba, and Hirofumi Kanoh, and Katsumi Kaneko
Department of Chemistry, Graduate School of Science, Chiba University, Chiba 263-8522, Japan.

I2 was adsorbed on single-walled carbon nanotube from ethanol solution at 303 K. The I2 adsorption isotherm was Langmuirian, giving 35 (+/-10) mg g(-1) of the saturated adsorption amount (coverage 0.06-0.09). The I2-adsorption treatment of SWCNT bundles reduced the N2 adsorption amount at 77 K by only 3%; the adsorption amount of supercritical H2 at 77 K was decreased by 30% because of the I2-adsorption treatment, indicating the blocking of interstitial pores by adsorbed I2. These adsorption results indicated the adsorption of I2 molecules in the narrow interstitial pores. The I2-adsorption treatment increases the Raman intensity coming from metallic SWCNTs, and the dc electrical conductivity increased by 15% because of the I2-adsorption treatment, strongly suggesting the presence of charge-transfer interaction between I2 and SWCNTs irrespective of small coverage by I2.

UI MeSH Term Description Entries

Related Publications

Chiharu Hayakawa, and Koki Urita, and Tomonori Ohba, and Hirofumi Kanoh, and Katsumi Kaneko
March 2013, Nanotoxicology,
Chiharu Hayakawa, and Koki Urita, and Tomonori Ohba, and Hirofumi Kanoh, and Katsumi Kaneko
March 2023, Nanomaterials (Basel, Switzerland),
Chiharu Hayakawa, and Koki Urita, and Tomonori Ohba, and Hirofumi Kanoh, and Katsumi Kaneko
September 2020, Toxicology mechanisms and methods,
Chiharu Hayakawa, and Koki Urita, and Tomonori Ohba, and Hirofumi Kanoh, and Katsumi Kaneko
March 2004, The Journal of chemical physics,
Chiharu Hayakawa, and Koki Urita, and Tomonori Ohba, and Hirofumi Kanoh, and Katsumi Kaneko
August 2013, Dalton transactions (Cambridge, England : 2003),
Chiharu Hayakawa, and Koki Urita, and Tomonori Ohba, and Hirofumi Kanoh, and Katsumi Kaneko
October 1998, Science (New York, N.Y.),
Chiharu Hayakawa, and Koki Urita, and Tomonori Ohba, and Hirofumi Kanoh, and Katsumi Kaneko
May 2009, Journal of physics. Condensed matter : an Institute of Physics journal,
Chiharu Hayakawa, and Koki Urita, and Tomonori Ohba, and Hirofumi Kanoh, and Katsumi Kaneko
October 2010, Nanoscale,
Chiharu Hayakawa, and Koki Urita, and Tomonori Ohba, and Hirofumi Kanoh, and Katsumi Kaneko
April 2010, The journal of physical chemistry. B,
Chiharu Hayakawa, and Koki Urita, and Tomonori Ohba, and Hirofumi Kanoh, and Katsumi Kaneko
January 2009, Langmuir : the ACS journal of surfaces and colloids,
Copied contents to your clipboard!