Occurrence and removal of organic micropollutants in the treatment of landfill leachate by combined anaerobic-membrane bioreactor technology. 2008

Yiping Xu, and Yiqi Zhou, and Donghong Wang, and Shaohua Chen, and Junxin Liu, and Zijian Wang
State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. ypxu@rcees.ac.cn

Organic micropollutants, with high toxicity and environmental concern, are present in the landfill leachate at much lower levels than total organic constituents (chemical oxygen demand (COD), biochemical oxygen demand (BOD), or total organic carbon (TOC)), and few has been known for their behaviors in different treatment processes. In this study, occurrence and removal of 17 organochlorine pesticides (OCPs), 16 polycyclic aromatic hydrocarbons (PAHs), and technical 4-nonylphenol (4-NP) in landfill leachate in a combined anaerobic-membrane bioreactor (MBR) were investigated. Chemical analyses were performed in leachates sampled from different treatment processes, using solid-phase extraction and gas chromatography with electron capture detector and mass spectrometry. Concentrations of OCPs, PAHs, and 4-NP in the raw leachate were detected within the range from ND (not detected) to 595.2 ng/L, which were as low as only 10(-7)-10(-5) percentage of TOC (at the concentration of 2,962 mg/L). The removal of 4-NP was mainly established in the MBR process, in agreement with removals of COD, BOD, and TOC. However, the removals of OCPs and PAHs were different, mainly achieved in the anaerobic process. High removal efficiencies of both total organic constituents and organic micropollutants could be achieved by the combined anaerobic-MBR technology. The removal efficiencies of total organic constituents were in the order of BOD (99%) > COD (89%) > TOC (87%), whereas the removal efficiencies of investigated organic micropollutants were as follows: OCPs (94%) > 4-NP (77%) > PAHs (59%).

UI MeSH Term Description Entries
D008567 Membranes, Artificial Artificially produced membranes, such as semipermeable membranes used in artificial kidney dialysis (RENAL DIALYSIS), monomolecular and bimolecular membranes used as models to simulate biological CELL MEMBRANES. These membranes are also used in the process of GUIDED TISSUE REGENERATION. Artificial Membranes,Artificial Membrane,Membrane, Artificial
D009930 Organic Chemicals A broad class of substances containing carbon and its derivatives. Many of these chemicals will frequently contain hydrogen with or without oxygen, nitrogen, sulfur, phosphorus, and other elements. They exist in either carbon chain or carbon ring form. Organic Chemical,Chemical, Organic,Chemicals, Organic
D002849 Chromatography, Gas Fractionation of a vaporized sample as a consequence of partition between a mobile gaseous phase and a stationary phase held in a column. Two types are gas-solid chromatography, where the fixed phase is a solid, and gas-liquid, in which the stationary phase is a nonvolatile liquid supported on an inert solid matrix. Chromatography, Gas-Liquid,Gas Chromatography,Chromatographies, Gas,Chromatographies, Gas-Liquid,Chromatography, Gas Liquid,Gas Chromatographies,Gas-Liquid Chromatographies,Gas-Liquid Chromatography
D000693 Anaerobiosis The complete absence, or (loosely) the paucity, of gaseous or dissolved elemental oxygen in a given place or environment. (From Singleton & Sainsbury, Dictionary of Microbiology and Molecular Biology, 2d ed) Anaerobic Metabolism,Anaerobic Metabolisms,Anaerobioses,Metabolism, Anaerobic,Metabolisms, Anaerobic
D001673 Biodegradation, Environmental Elimination of ENVIRONMENTAL POLLUTANTS; PESTICIDES and other waste using living organisms, usually involving intervention of environmental or sanitation engineers. Bioremediation,Phytoremediation,Natural Attenuation, Pollution,Environmental Biodegradation,Pollution Natural Attenuation
D014874 Water Pollutants, Chemical Chemical compounds which pollute the water of rivers, streams, lakes, the sea, reservoirs, or other bodies of water. Chemical Water Pollutants,Landfill Leachate,Leachate, Landfill,Pollutants, Chemical Water
D018508 Water Purification Any of several processes in which undesirable impurities in water are removed or neutralized; for example, chlorination, filtration, primary treatment, ion exchange, and distillation. It includes treatment of WASTEWATER to provide potable and hygienic water in a controlled or closed environment as well as provision of public drinking water supplies. Waste Water Purification,Waste Water Treatment,Wastewater Purification,Wastewater Treatment,Water Treatment,Purification, Waste Water,Purification, Wastewater,Purification, Water,Treatment, Waste Water,Treatment, Wastewater,Treatment, Water,Waste Water Purifications,Waste Water Treatments,Water Purification, Waste
D019149 Bioreactors Tools or devices for generating products using the synthetic or chemical conversion capacity of a biological system. They can be classical fermentors, cell culture perfusion systems, or enzyme bioreactors. For production of proteins or enzymes, recombinant microorganisms such as bacteria, mammalian cells, or insect or plant cells are usually chosen. Fermentors,Bioreactor,Fermentor

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