Electrostatic interaction between two cylindrical soft particles. 2009

Hiroyuki Ohshima, and Atsushi Hyono
Faculty of Pharmaceutical Sciences, Tokyo University of Science, 2641 Yamazaki, Noda, Chiba 278-8510, Japan. ohshima@rs.noda.tus.ac.jp

An expression for the potential energy of electrostatic interaction between two soft cylinders (i.e., polyelectrolyte-coated cylindrical particles) in an electrolyte solution is derived by applying Derjaguin's approximation to the corresponding interaction energy between two parallel soft plates for the case where the density of fixed charges within the polyelectrolyte layer is low. The interaction between two parallel cylinders and that between two crossed cylinders are considered. The obtained expression covers various limiting cases that include hard cylinder/hard cylinder interaction, cylindrical polyelectrolyte/cylindrical polyelectrolyte interaction, soft cylinder/cylindrical polyelectrolyte interaction, soft cylinder/hard cylinder interaction, and cylindrical polyelectrolyte/hard cylinder interaction.

UI MeSH Term Description Entries
D010316 Particle Size Relating to the size of solids. Particle Sizes,Size, Particle,Sizes, Particle
D011108 Polymers Compounds formed by the joining of smaller, usually repeating, units linked by covalent bonds. These compounds often form large macromolecules (e.g., BIOPOLYMERS; PLASTICS). Polymer
D004573 Electrolytes Substances that dissociate into two or more ions, to some extent, in water. Solutions of electrolytes thus conduct an electric current and can be decomposed by it (ELECTROLYSIS). (Grant & Hackh's Chemical Dictionary, 5th ed) Electrolyte
D013499 Surface Properties Characteristics or attributes of the outer boundaries of objects, including molecules. Properties, Surface,Property, Surface,Surface Property
D055672 Static Electricity The accumulation of an electric charge on a object Electrostatic,Electrostatics,Static Charge,Charge, Static,Charges, Static,Electricity, Static,Static Charges

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