BIOMAT Database Logo BIOMAT Database Logo

X-ray structure of 1,3,4-tri-O-acetyl-2-deoxy-beta-d-erythro-pentopyranose. 2009

Ji-Jun Chen, and Jian-Rong Gao, and Liang Han, and Jian-Hong Jia, and Wei-Jian Sheng, and Yu-Jing Li
Zhejiang University of Technology, Hang Zhou, PR China.

Peracetylated 2-deoxy-d-erythro-pentose (2-deoxy-d-ribose) was synthesized through the acetylation of 2-deoxy-d-ribose with acetic anhydride in pyridine, and the products (including all four ring forms) exist in form of either a white solid or a syrup. A single crystal of 1,3,4-tri-O-acetyl-2-deoxy-beta-d-erythro-pentopyranose was obtained from the syrup and its structure was determined by X-ray diffraction. The crystal adopts the (1)C(4) conformation, presenting an orthorhombic system, space group P2(1)2(1)2(1) with Z=4, unit cell dimensions a=7.2274 (3)A, b=8.0938 (5)A, and c=22.0517 (11)A.

UI MeSH Term Description Entries
D009005 Monosaccharides Single chain carbohydrates that are the most basic units of CARBOHYDRATES. They are typically colorless crystalline substances with a sweet taste and have the same general formula CnH2nOn. Monosaccharide,Simple Sugar,Simple Sugars,Sugar, Simple,Sugars, Simple
D002236 Carbohydrate Conformation The characteristic 3-dimensional shape of a carbohydrate. Carbohydrate Linkage,Carbohydrate Conformations,Carbohydrate Linkages,Conformation, Carbohydrate,Conformations, Carbohydrate,Linkage, Carbohydrate,Linkages, Carbohydrate
D012266 Ribose A pentose active in biological systems usually in its D-form. D-Ribose,D Ribose
D015394 Molecular Structure The location of the atoms, groups or ions relative to one another in a molecule, as well as the number, type and location of covalent bonds. Structure, Molecular,Molecular Structures,Structures, Molecular
D018360 Crystallography, X-Ray The study of crystal structure using X-RAY DIFFRACTION techniques. (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) X-Ray Crystallography,Crystallography, X Ray,Crystallography, Xray,X Ray Crystallography,Xray Crystallography,Crystallographies, X Ray,X Ray Crystallographies

Related Publications

Ji-Jun Chen, and Jian-Rong Gao, and Liang Han, and Jian-Hong Jia, and Wei-Jian Sheng, and Yu-Jing Li
Synthesis of 2-Acetamido-1,3,4-Tri-O-Acetyl-2-Deoxy-D-Mannopyranose -6-Phosphate Prodrugs as Potential Therapeutic Agents.
August 2022, Current protocols,
Ji-Jun Chen, and Jian-Rong Gao, and Liang Han, and Jian-Hong Jia, and Wei-Jian Sheng, and Yu-Jing Li
3-O-acetyl-4-deoxy-4-iodo-beta-D-fructofuranosyl 2,3,6-tri-o-acetyl-4-chloro-4-deoxy-alpha-D-glucopyranoside.
September 2001, Acta crystallographica. Section C, Crystal structure communications,
Ji-Jun Chen, and Jian-Rong Gao, and Liang Han, and Jian-Hong Jia, and Wei-Jian Sheng, and Yu-Jing Li
1,3,4-Tri-O-acetyl-2-N-(tri-fluoro-acetyl)-β-l-fucose.
February 2014, Acta crystallographica. Section E, Structure reports online,
Ji-Jun Chen, and Jian-Rong Gao, and Liang Han, and Jian-Hong Jia, and Wei-Jian Sheng, and Yu-Jing Li
Synthesis of anomers of 6-O-tosyl-1,3,4-tri-O-acetyl-N-acetyl-D-glucosamine and 1,6-anhydro-N-acetyl-beta-D-glucosamin.
November 1962, Chemical & pharmaceutical bulletin,
Ji-Jun Chen, and Jian-Rong Gao, and Liang Han, and Jian-Hong Jia, and Wei-Jian Sheng, and Yu-Jing Li
N-(2-Acetamido-3,4,6-tri-O-acetyl-2-deoxy-alpha-D-galactopyranosyloxy)succinimide.
May 2001, Acta crystallographica. Section C, Crystal structure communications,
Ji-Jun Chen, and Jian-Rong Gao, and Liang Han, and Jian-Hong Jia, and Wei-Jian Sheng, and Yu-Jing Li
Use of O-(2,3,4-tri-O-acetyl-alpha-L-fucopyranosyl)-(1----3)-O-(2-acetamido- 4,6-di-O-acetyl-2-deoxy-beta-D-glucopyranosyl)-(1----3)-2,4,6-tri-O- acetyl-alpha-D-galactopyranosyl bromide as a glycosyl donor. Synthesis of 4-nitrophenyl O-alpha-L-fucopyranosyl-(1----3)-O-(2-acetamido-2-deoxy-beta-D- glucopyranosyl)-(1----3)-beta-D-galactopyranoside.
March 1988, Carbohydrate research,
Ji-Jun Chen, and Jian-Rong Gao, and Liang Han, and Jian-Hong Jia, and Wei-Jian Sheng, and Yu-Jing Li
[Mass spectra of N1-acyl derivatives of 2-acetamino-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyranosylamine].
January 1970, Justus Liebigs Annalen der Chemie,
Ji-Jun Chen, and Jian-Rong Gao, and Liang Han, and Jian-Hong Jia, and Wei-Jian Sheng, and Yu-Jing Li
Crystal structure and solid-state NMR analysis of methyl 2,3,6-tri-O-acetyl-2-deoxy-2-[3-(2-phenylethyl)-ureido]-beta-D- glucopyranoside.
February 1996, Carbohydrate research,
Ji-Jun Chen, and Jian-Rong Gao, and Liang Han, and Jian-Hong Jia, and Wei-Jian Sheng, and Yu-Jing Li
Solution and solid-state structure of N-acetamido-3,4,6-tri-O-acetyl-2-azido-2-deoxy-alpha-D-galactopyranosylamine.
June 2004, Carbohydrate research,
Ji-Jun Chen, and Jian-Rong Gao, and Liang Han, and Jian-Hong Jia, and Wei-Jian Sheng, and Yu-Jing Li
Preparation, chemical and crystal structures of N-(2-acetamido-3,4,6-tri-O-acetyl-2-deoxy-beta-D-glucopyranosyl)pyridinium chloride.
November 2000, Carbohydrate research,
Copied contents to your clipboard!