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The key intermediate in the amination of saturated C-H bonds: synthesis, X-ray characterization and catalytic activity of Ru(TPP)(NAr)(2) (Ar = 3,5-(CF(3))(2)C(6)H(3)). 2009

Simone Fantauzzi, and Emma Gallo, and Alessandro Caselli, and Fabio Ragaini, and Nicola Casati, and Piero Macchi, and Sergio Cenini
Dipartimento di Chimica Inorganica, Metallorganica e Analitica L Malatesta, Università di Milano and ISTM-CNR, Milano, Italy.

The complex Ru(TPP)(NAr)(2) inserts a nitrene group into allylic and benzylic C-H bonds and is the key intermediate in the ruthenium porphyrin-catalyzed amination of hydrocarbons by aryl azides.

UI MeSH Term Description Entries

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