Mechanically induced biaxial transition in a nanoconfined nematic liquid crystal with a topological defect. 2009

Giovanni Carbone, and Giuseppe Lombardo, and Riccardo Barberi, and Igor Musevic, and Uros Tkalec
CNR-INFM LiCryL, c/o Physics Department, University of Calabria, 87036 Rende (CS), Italy. giovanni.carbone@eng.ox.ac.uk

Using an atomic force microscopy, we have measured the separation dependence of the force between an atomically flat mica sheet and a micrometer-sized glass sphere immersed in the nematic liquid crystal. As the mica surface induces a strong parallel alignment and the treated glass sphere induces a strong perpendicular alignment on the liquid crystal, a repulsive force is observed due to the elastically deformed nematic liquid crystal. We observe that below a critical separation d(th) approximately 10 nm, the system undergoes a structural transition, thus relaxing the distortion. The results are interpreted within the eigenvalue exchange mechanism using the Landau-de Gennes tensorial approach.

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