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Stepwise assembly of a bis-hydroxylaminato gallium-indium complex. 2010

Patrick Bösing, and Norbert W Mitzel
Fakultät für Chemie, Lehrstuhl für Anorganische Chemie und Strukturchemie, Universität Bielefeld, Universitätsstrasse 25, 33615, Bielefeld, Germany.

A heterobimetallic gallium-indium complex with five-coordinate InMe group bonded via two O and two N atoms to a [GaR(2)ON(Me)(CH(2))(2)N(Me)O](2) macrocycle resulted from the reaction of the OH- and NH-functional bishydroxylaminato complex of gallium, MeN(OH)(CH(2))(2)N(H)(Me)OGaR(2)O-cyclo[N(Me)(CH(2))(2)N(Me)OGaR(2)] (R = (t)Bu) with InMe(3), whereas the reaction of the latter with Me(3)N x AlH(3) affords a gallium hydride with Ga-Ga bonds.

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