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Dipyrrin based luminescent cyclometallated palladium and platinum complexes. 2010
Catherine Bronner, and
Stéphane A Baudron, and
Mir Wais Hosseini, and
Cristian A Strassert, and
Aurélie Guenet, and
Luisa De Cola
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université de Strasbourg, F-67000, Strasbourg, France.
A series of complexes based on the combination of cyclometallated palladium or platinum moieties with functionalized dipyrrin ligands bearing mesityl- or benzonitrile groups have been prepared and characterized both in the solid state and in solution; these compounds exhibit a characteristic dipyrrin-centered luminescence with an emission intensity modulated by the degree of rotational freedom of the aromatic group attached to the dipyrrin chelate.
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