Infrared and Raman spectra of AA-stacking bilayer graphene. 2010

Yuehua Xu, and Xiaowei Li, and Jinming Dong
Group of Computational Condensed Matter Physics, National Laboratory of Solid State Microstructures and Department of Physics, Nanjing University, Nanjing, People's Republic of China.

The infrared (IR) absorption and resonant Raman spectra of the undoped AA-stacking bilayer graphene have been calculated using density-functional theory in the local density approximation. It is found that the undoped AA-stacking bilayer graphene exhibits a different characteristic jump and peak structure in its IR spectra, and a different G-band peak structure in its resonant Raman spectra, compared with those of the AB-stacking one, which are caused by the different interlayer coupling effects, due to different stacking types in both of them. Based upon the different IR and Raman spectra, a powerful experimental method can be proposed to identify accurately the stacking type and the layer number in future experiments.

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