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Reversible complexation of isocyanides by the distannyne Ar'SnSnAr' (Ar' = C(6)H(3)-2,6(C(6)H(3)-2,6-(i)Pr(2))(2)). 2010

Yang Peng, and Xinping Wang, and James C Fettinger, and Philip P Power
Department of Chemistry, University of California, Davis, CA 95616, USA.

The reaction of the distannyne Ar'SnSnAr' (Ar' = C(6)H(3)-2,6(C(6)H(3)-2,6-(i)Pr(2))(2)) with tert-butyl or mesityl isocyanide afforded the bis-adducts Ar'SnSnAr'(CNBu(t))(2) or Ar'SnSnAr' (CNMes)(2) in which the isonitriles are reversibly bound under ambient conditions.

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