Ammonium biosorption onto sawdust: FTIR analysis, kinetics and adsorption isotherms modeling. 2010

Mohamed Ali Wahab, and Salah Jellali, and Naceur Jedidi
Water Research and Technologies Centre (CERTE), Wastewater Treatment and Recycling Laboratory, Tunisia. waheb_med@yahoo.fr

Sawdust, an available and renewable biomass, was investigated as a novel ammonium biosorbent. Biosorption occurred over a pH range of 6-10, reached an equilibrium state within only 20 min, and can be described by a pseudo-second-order model predicting a chemisorption process. Equilibrium data were very well represented by Langmuir isotherm and confirm monolayer coverage. FTIR analysis before and after biosorption of ammonium onto sawdust suggested that the main mechanisms involved in the removal of ammonium might be the ionic exchange and complexation. The use of sawdust presents an interesting option for both tertiary wastewater treatment (as a possible non-conventional biosorbent for the removal of ammonium), and waste recycling (as a fertilizer and compost).

UI MeSH Term Description Entries
D007700 Kinetics The rate dynamics in chemical or physical systems.
D011522 Protons Stable elementary particles having the smallest known positive charge, found in the nuclei of all elements. The proton mass is less than that of a neutron. A proton is the nucleus of the light hydrogen atom, i.e., the hydrogen ion. Hydrogen Ions,Hydrogen Ion,Ion, Hydrogen,Ions, Hydrogen,Proton
D002118 Calcium A basic element found in nearly all tissues. It is a member of the alkaline earth family of metals with the atomic symbol Ca, atomic number 20, and atomic weight 40. Calcium is the most abundant mineral in the body and combines with phosphorus to form calcium phosphate in the bones and teeth. It is essential for the normal functioning of nerves and muscles and plays a role in blood coagulation (as factor IV) and in many enzymatic processes. Coagulation Factor IV,Factor IV,Blood Coagulation Factor IV,Calcium-40,Calcium 40,Factor IV, Coagulation
D004058 Diffusion The tendency of a gas or solute to pass from a point of higher pressure or concentration to a point of lower pressure or concentration and to distribute itself throughout the available space. Diffusion, especially FACILITATED DIFFUSION, is a major mechanism of BIOLOGICAL TRANSPORT. Diffusions
D006863 Hydrogen-Ion Concentration The normality of a solution with respect to HYDROGEN ions; H+. It is related to acidity measurements in most cases by pH pH,Concentration, Hydrogen-Ion,Concentrations, Hydrogen-Ion,Hydrogen Ion Concentration,Hydrogen-Ion Concentrations
D000327 Adsorption The adhesion of gases, liquids, or dissolved solids onto a surface. It includes adsorptive phenomena of bacteria and viruses onto surfaces as well. ABSORPTION into the substance may follow but not necessarily. Adsorptions
D000644 Quaternary Ammonium Compounds Derivatives of ammonium compounds, NH4+ Y-, in which all four of the hydrogens bonded to nitrogen have been replaced with hydrocarbyl groups. These are distinguished from IMINES which are RN Quaternary Ammonium Compound,Ammonium Compound, Quaternary,Ammonium Compounds, Quaternary,Compound, Quaternary Ammonium
D001673 Biodegradation, Environmental Elimination of ENVIRONMENTAL POLLUTANTS; PESTICIDES and other waste using living organisms, usually involving intervention of environmental or sanitation engineers. Bioremediation,Phytoremediation,Natural Attenuation, Pollution,Environmental Biodegradation,Pollution Natural Attenuation
D013696 Temperature The property of objects that determines the direction of heat flow when they are placed in direct thermal contact. The temperature is the energy of microscopic motions (vibrational and translational) of the particles of atoms. Temperatures
D014865 Waste Disposal, Fluid The discarding or destroying of liquid waste products or their transformation into something useful or innocuous. Disposal, Fluid Waste,Disposals, Fluid Waste,Fluid Waste Disposal,Fluid Waste Disposals,Waste Disposals, Fluid

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