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N-heterocyclic carbene-ruthenium complexes for the racemization of chiral alcohols. 2010

Johann Bosson, and Steven P Nolan
EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews KY16 9ST, UK.

The activity of well-defined 16-electron ruthenium complexes bearing an N-heterocyclic carbene ligand in the racemization of chiral alcohols is reported. Mechanistic considerations are also presented.

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