BIOMAT Database Logo BIOMAT Database Logo

Complementary halogen and hydrogen bonding: sulfur...iodine interactions and thioamide ribbons. 2010

Hadi D Arman, and Rebecca L Gieseking, and Timothy W Hanks, and William T Pennington
Department of Chemistry, Clemson University, Clemson, SC, USA.

Complementary halogen bonding and hydrogen bonding coexist in co-crystals of organoiodines with molecules containing the thioamide functionality. Thiourea.organoiodine co-crystals are shown to exhibit a remarkably reliable synthon with complementary N-H...S ribbons and S...I interactions.

UI MeSH Term Description Entries
D007455 Iodine A nonmetallic element of the halogen group that is represented by the atomic symbol I, atomic number 53, and atomic weight of 126.90. It is a nutritionally essential element, especially important in thyroid hormone synthesis. In solution, it has anti-infective properties and is used topically. Iodine-127,Iodine 127
D008968 Molecular Conformation The characteristic three-dimensional shape of a molecule. Molecular Configuration,3D Molecular Structure,Configuration, Molecular,Molecular Structure, Three Dimensional,Three Dimensional Molecular Structure,3D Molecular Structures,Configurations, Molecular,Conformation, Molecular,Conformations, Molecular,Molecular Configurations,Molecular Conformations,Molecular Structure, 3D,Molecular Structures, 3D,Structure, 3D Molecular,Structures, 3D Molecular
D006219 Halogens A family of nonmetallic, generally electronegative, elements that form group 17 (formerly group VIIa) of the periodic table. Halogen,Group 17 Elements,Elements, Group 17
D006860 Hydrogen Bonding A low-energy attractive force between hydrogen and another element. It plays a major role in determining the properties of water, proteins, and other compounds. Hydrogen Bonds,Bond, Hydrogen,Hydrogen Bond
D013455 Sulfur An element that is a member of the chalcogen family. It has an atomic symbol S, atomic number 16, and atomic weight [32.059; 32.076]. It is found in the amino acids cysteine and methionine. Sulfur-16,Sulfur 16
D013854 Thioamides Organic compounds containing the radical -CSNH2. Thioamide
D018360 Crystallography, X-Ray The study of crystal structure using X-RAY DIFFRACTION techniques. (McGraw-Hill Dictionary of Scientific and Technical Terms, 4th ed) X-Ray Crystallography,Crystallography, X Ray,Crystallography, Xray,X Ray Crystallography,Xray Crystallography,Crystallographies, X Ray,X Ray Crystallographies

Related Publications

Hadi D Arman, and Rebecca L Gieseking, and Timothy W Hanks, and William T Pennington
Carboxylic Acid to Thioamide Hydrogen Bonding.
January 2009, Tetrahedron,
Hadi D Arman, and Rebecca L Gieseking, and Timothy W Hanks, and William T Pennington
Halogen Bonding in Hypervalent Iodine Compounds.
January 2016, Topics in current chemistry,
Hadi D Arman, and Rebecca L Gieseking, and Timothy W Hanks, and William T Pennington
Glycoluril ribbons tethered by complementary hydrogen bonds.
July 2003, Chemical communications (Cambridge, England),
Hadi D Arman, and Rebecca L Gieseking, and Timothy W Hanks, and William T Pennington
Hydrogen bonding vs. halogen bonding: the solvent decides.
August 2017, Chemical science,
Hadi D Arman, and Rebecca L Gieseking, and Timothy W Hanks, and William T Pennington
Electrostatically enhanced FF interactions through hydrogen bonding, halogen bonding and metal coordination: an ab initio study.
July 2016, Physical chemistry chemical physics : PCCP,
Hadi D Arman, and Rebecca L Gieseking, and Timothy W Hanks, and William T Pennington
Iodine(III) Derivatives as Halogen Bonding Organocatalysts.
March 2018, Angewandte Chemie (International ed. in English),
Hadi D Arman, and Rebecca L Gieseking, and Timothy W Hanks, and William T Pennington
Refined SMD Parameters for Bromine and Iodine Accurately Model Halogen-Bonding Interactions in Solution.
October 2018, Chemistry (Weinheim an der Bergstrasse, Germany),
Hadi D Arman, and Rebecca L Gieseking, and Timothy W Hanks, and William T Pennington
Activation of hydrogen- and halogen-bonding interactions in tetrathiafulvalene-based crystalline molecular conductors.
November 2004, Chemical reviews,
Hadi D Arman, and Rebecca L Gieseking, and Timothy W Hanks, and William T Pennington
Electronic criterion for categorizing the chalcogen and halogen bonds: sulfur-iodine interactions in crystals.
April 2019, Acta crystallographica Section B, Structural science, crystal engineering and materials,
Hadi D Arman, and Rebecca L Gieseking, and Timothy W Hanks, and William T Pennington
Halogen Bonding versus Hydrogen Bonding: A Molecular Orbital Perspective.
April 2012, ChemistryOpen,
Copied contents to your clipboard!